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| Cotte, Laura; Waeles, Mathieu; Pernet-coudrier, Benoit; Sarradin, Pierre-marie; Cathalot, Cecile; Riso, Ricardo D.. |
| The objective of this study was to assess the impact of the filtration method (in situ vs. ex situ) on the dissolved/particulate partitioning of 12 elements in hydrothermal samples collected from the Lucky Strike vent field (Mid-Atlantic Ridge; MAR). To do so, dissolved ( <0.45 mu m) and particulate Mg, Li, Mn, U, V, As, Ba, Fe, Zn, Cd, Pb and Cu were measured using different techniques (HR-ICP-MS, ICP-AES and CCSA). Using in situ filtration as a baseline, we showed that ex situ filtration (on-board and on shore after freezing) resulted in an underestimation of the dissolved pool, which was counterbalanced by an overestimation of the particulate pool for almost all the elements studied. We also showed that on-board filtration was acceptable for the... |
| Tipo: Text |
Palavras-chave: Metal; Hydrothermal vent; Dissolved; Particulate; Filtration method. |
| Ano: 2015 |
URL: https://archimer.ifremer.fr/doc/00298/40970/42656.pdf |
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| Waeles, Mathieu; Cotte, Laura; Pernet-coudrier, Benoit; Chavagnac, V.; Cathalot, Cecile; Leleu, T.; Laes-huon, Agathe; Perhirin, Antoine; Riso, R. D.; Sarradin, Pierre-marie. |
| Deep-sea hydrothermal venting is now recognized as a major source of iron (Fe), an essential trace element that controls marine productivity. However, the reactions occurring during dispersal from buoyant plumes to neutrally buoyant hydrothermal plumes are still poorly constrained. Here we report for the first time on the dissolved-particulate partition of Fe after in situ filtration at the early stage of mixing at different hydrothermal discharges, i.e., Lucky Strike (37 degrees N), TAG (26 degrees N), and Snakepit (23 degrees N) on the Mid-Atlantic Ridge. We found that hydrothermal iron is almost completely preserved (>90%) in the dissolved fraction, arguing for low iron-bearing sulfide precipitation of iron in basalt-hosted systems with low Fe:H2S... |
| Tipo: Text |
Palavras-chave: Hydrothermal; Iron; Sulfide; Venting; Filtration; Precipitation. |
| Ano: 2017 |
URL: https://archimer.ifremer.fr/doc/00388/49944/50522.pdf |
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| Cotte, Laura; Omanovic, Dario; Waeles, Mathieu; Laes, Agathe; Cathalot, Cecile; Sarradin, Pierre-marie; Riso, Ricardo D.. |
| Environmental contextCopper released by deep-sea hydrothermal vents has been recognised to be partly stabilised against precipitation by its complexation with strong Cu binding ligands. Yet, the sources and nature of these compounds in such environments are still not fully understood. This study shows that the Cu ligands detected are hydrothermally sourced and could be mainly inorganic sulfur species. AbstractThe apparent speciation of Cu in the early buoyant plume of two black smokers (Aisics and Y3) from the hydrothermal vent field Lucky Strike (Mid-Atlantic Ridge) was investigated using competitive ligand exchange-adsorptive cathodic stripping voltammetry (CLE-AdCSV). We have assessed the apparent Cu-binding ligand concentration ([L]) and the... |
| Tipo: Text |
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| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00444/55558/57208.pdf |
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| Chavagnac, Valerie; Ali, Hassan Saleban; Jeandel, Catherine; Leleu, Thomas; Destrigneville, Christine; Castillo, Alain; Cotte, Laura; Waeles, Mathieu; Cathalot, Cecile; Laes, Agathe; Pelleter, Ewan; Nonnotte, Philippe; Sarradin, Pierre-marie; Cannat, Mathilde. |
| While hydrothermal vents are now thought to be a major source of dissolved iron to the oceans, they have always been considered to be a sink for the dissolved rare-earth elements (DREEs). However, true dissolved REE observations in hydrothermal plumes are still lacking. Here we report for the first time the DREE concentrations and neodymium isotopic compositions (DεNd) of buoyant hydrothermal fluids at Lucky Strike (Mid-Atlantic Ridge). We find that 27 to 62% of total hydrothermal DREEs are rapidly scavenged by anhydrite precipitation at the onset of buoyant plume formation. After this initial loss, all DREEs behave quasi-conservatively within the buoyant plume. Dissolved phase εNd (DεNd) in the evolving plume are identical to black smoker DεNd of +9.0 and... |
| Tipo: Text |
Palavras-chave: Black smokers; Rare earth elements; Neodymium isotopes; Hydrothermal; Sulfate minerals; EMSO-Azores. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00456/56733/58511.pdf |
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